pH-Dependent two novel 3D polynuclear cobalt(II) cluster-based metal-organic frameworks constructed from a tri-pyridyl-bis-amide and a polycarboxylate: assembly, structures and properties

RSC Adv., 2013, Accepted Manuscript
DOI: 10.1039/C3RA41552J, Paper

Xiuli Wang, Jingjing Huang, Lianli Liu, Guocheng Liu, Hongyan Lin, Juwen Zhang, Naili Chen, Yun Qu
The hydrothermal reaction of CoCl2 with N,N'-bis(pyridine-3-yl)pyridine-3,5-dicarboxamide (L) and 1,3,5-benzenetricarboxylic acid (H3BTC) mixed ligands affords two novel polynuclear cobalt cluster-based metal-organic frameworks (MOFs), [Co3(L)2(BTC)2(H2O)2][round bullet, filled]6H2O (1) and {[Co2(L)(BTC)(OH)][round bullet, filled]2.5H2O}2 (2). Single crystal...
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